Transforming Fossil Fuels into Heat or Hydrogen

Greenhouse gases, in particular CO2 are the main cause of climate change. This project was motivated by finding an alternative way of using natural gas to produce heat for industrial facilities with reduced CO2 production. The main purpose of this project was to investigate pyrolysis of natural gas with a mediu-scale set-up (8 kw). Natural gas can be decomposed into hydrogen and carbon black at high temperatures.


Hydrogen can be used as a clean fuel and carbon black is a valuable raw material for many industries such as tire, rubber, ink and pigments.


Two natural gas thermal decomposition systems will be investigated in order to transform fossil fuels into either heat or hydrogen:


1) Gas-phase pyrolysis, where the heat for pyrolysis is provided by burning natural gas and the pyrolysis occurs via heat transfer from the gas-phase products of combustion.


2) Molten-metal pyrolysis where natural gas is bubbled through molten metal which could be heated from a variety of heat sources (e.g., solar).

Analysis of the products and kinetic rates of methane thermal decomposition. Part II: Numerical models

Jason Olfert, Marc Secanell, Larry Kostiuk, Ambuj Punia, James Tatum

Conference Proceedings

Analysis of the products and kinetic rates of methane thermaldecomposition. Part I: Experimental apparatus

Jason Olfert, Marc Secanell, Larry Kostiuk, Ambuj Punia, James Tatum

Conference Proceedings

Experimental Investigation of Carbon Black Properties Produced by the Thermal Decomposition of Methane in the Products of Premixed Flames

Mohammad Afroughi

Masters Thesis

Experimental and numerical analysis of a methane thermal decomposition reactor

Marc Secanell, Larry Kostiuk

Article in professional or trade journals

Experimental study of methane decarbonization to produce hydrogen using a laminar premixed flame

Farjad Falahati

Masters Thesis

Nanoparticle Emission Characteristics during Methane Pyrolysis in a Laminar Premixed Flame

Jason Olfert, Larry Kostiuk, Mohammad Afroughi, Farjad Falahati

Conference Proceedings

Preliminary experimental study of methane decarbonization using a laminar premixed flame

Jason Olfert, Larry Kostiuk, Mohammad Afroughi, Farjad Falahati

Conference Proceedings

Properties of carbon black produced by the thermal decomposition of methane in the products of premixed flames

Jason Olfert, Larry Kostiuk, Mohammad Afroughi, Farjad Falahati

Scholarly Refereed Journal

Properties of carbon particles generated by methane decarbonization in oxygen deficient gas streams

Jason Olfert, Larry Kostiuk, Mohammad Afroughi, Farjad Falahati

Conference Proceedings