All-solid Li batteries offer improved safety and power density yet suffer from drastic capacity fade, a result of electrolyte decomposition on electrode surfaces. We will introduce/optimize an interfacial protective layer that provides Li+ transport pathways and prevents direct exposure of solid electrolyte to extreme potentials. Our unique, in-situ approach allows real-time reaction monitoring during operation. Combined with the battery performance tests, the insights gained will facilitate rational protective layer design. Interlayer materials of interest include: 1) Li+ solvates exhibiting excellent stability at operating temperature, (10 – 50 C) and 2) LiAlS thin films prepared via atomic layer deposition.
Characterizations of dynamic interfaces in all-solid lithium batteries
Article in professional or trade journals
Hot hole transfer from Ag nanoparticles to multiferroic YMn2O5 nanowires enables superior photocatalytic activity
Scholarly Refereed Journal
In Situ Strain Measurement in Solid-State Li-Ion Battery Electrodes
Article in professional or trade journals