All-solid Li batteries offer improved safety and power density yet suffer from drastic capacity fade, a result of electrolyte decomposition on electrode surfaces. We will introduce/optimize an interfacial protective layer that provides Li+ transport pathways and prevents direct exposure of solid electrolyte to extreme potentials. Our unique, in-situ approach allows real-time reaction monitoring during operation. Combined with the battery performance tests, the insights gained will facilitate rational protective layer design. Interlayer materials of interest include: 1) Li+ solvates exhibiting excellent stability at operating temperature, (10 – 50 C) and 2) LiAlS thin films prepared via atomic layer deposition.
Characterizations of dynamic interfaces in all-solid lithium batteries
Article in professional or trade journals
Hot hole transfer from Ag nanoparticles to multiferroic YMn2O5 nanowires enables superior photocatalytic activity
Peer-Reviewed Journal Article
In Situ Strain Measurement in Solid-State Li-Ion Battery Electrodes
Article in professional or trade journals